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A Waterwheel-Shaped meso–meso-Linked Porphyrin Pentamer

✍ Scribed by Chieh-Ao Wu; Chien-Lan Chiu; Chi-Lun Mai; You-Shiang Lin; Chen-Yu Yeh


Book ID
101837844
Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
232 KB
Volume
15
Category
Article
ISSN
0947-6539

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A convenient synthesis of a meso-tetraphenylporphyrin monoaldehyde, lc, is reported. Condensation of this aldehyde with excess benzaldehyde and pyrrole gives the bis-porphyrin 2. A low yield of the title compound, the penta-porphyrin 3 is obtained from lc and pyrrole in refluxing propionic acid. Re