## Abstract This is the sixth and final paper in the series under the above title. In prior papers, a VSE equation of state was proposed and applied to a variety of liquids at ambient pressure, but over broad ranges of temperature. Comparisons of thermodynamic quantities calculated from the equatio
A VSE equation of state for liquids—II: n-Alkanes, Benzene, Mercury and Water
✍ Scribed by Arthur K. Doolittle
- Book ID
- 103083849
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 576 KB
- Volume
- 301
- Category
- Article
- ISSN
- 0016-0032
No coin nor oath required. For personal study only.
✦ Synopsis
The work reported in Ref. (l), carried out on n-heptane from 273.16 K to the critical point (under moderate pressures), is extended to five n-alkanes, benzene, mercury and water under saturation pressures and extended to much lower temperatures. Forty calculations of various thermodynamic quantities pertaining to the liquids here studied (648 points) are presented in Tables II-IV. * All parameters and physical constants involved are presented in Table V. The Standard Percentage Errors (SPE) for all the calculations and the temperature ranges are given in Table VI. The grand average SPE for the 648 points is about one-third of 1%. Only one calculation (the temperature of water from 393.16 to 563.16 K) had an error greater than 1% (18 points).
📜 SIMILAR VOLUMES
## Abstract Our volume–entropy–energy (__VSE__) equation of state for liquids, first proposed in 1973 for use with low molecular weight homogeneous liquids, is here applied for the first time to a high molecular weight liquid that is heterogeneous in molecular weight, namely, a molten polymer. Four