𝔖 Bobbio Scriptorium
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A versatile synthesis of α, β -unsaturated aldehydes from tosylhydrazones.

✍ Scribed by P.C. Traas; H. Boelens; H.J. Takken


Publisher
Elsevier Science
Year
1976
Tongue
French
Weight
126 KB
Volume
17
Category
Article
ISSN
0040-4039

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Facile synthesis of β-alkyl-substituted
✍ Tsujiaki Hata; Masashi Nakajima; Mitsuo Sekine 📂 Article 📅 1979 🏛 Elsevier Science 🌐 French ⚖ 210 KB

8-Alkyl-substituted carboxylates were synthesized in good yields from U,B-unsaturated aldehydes by using the 1:l carbonyl adducts with diethyl bis(trimethylsily1) phosphite. Recently, several studies on acyl anion equivalents utilizing carbonyl insertion reactions have appeared. 2 It has been report