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A versatile strategy for the synthesis of N-linked glycoamino acids from glycals

✍ Scribed by Kumar, Vipin; Ramesh, Namakkal G.

Book ID
119941554
Publisher
Royal Society of Chemistry
Year
2007
Tongue
English
Weight
288 KB
Volume
5
Category
Article
ISSN
1477-0520

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Pi= Swern-type oxidation of various 7-halogenobicyclo[4.l.O]heptane-2,3-or -3,4- 10 s affords the corresponding bicyclic diketones which undergo in situ ring expansion and loss of hydrogen halide to give a-tropolones in high yieme quantitative conversion of the isolable 1,4-diketone 26 into the y-tr