✦ LIBER ✦
A Versatile Route to Porous Solids: Organic–Inorganic Hybrid Materials Assembled through Hydrogen Bonds
✍ Scribed by Christer B. Aakeröy; Alicia M. Beatty; Destin S. Leinen
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 176 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
✦ Synopsis
Square-planar and octahedral complexes of Ni and Pt link through head-to-head hydrogen bonds to form porous frameworks with large cavities that are suitable for inclusion of guest molecules. A series of four different complexes with pyridine-based ligands (in the center of the picture) are described, which contain either counterions or small molecules in channels. A=hydrogen-bond acceptor, D=hydrogen-bond donor, M=metal ion.