A versatile reagent for aldehyde synthesis. Methyl methylthiomethyl sulfoxide.
β Scribed by Katsuyuki Ogura; Gen-ichi Tsuchihashi
- Book ID
- 104248043
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- French
- Weight
- 213 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
β¦ Synopsis
Synthesis of aldehyde from formaldehyde mercaptal was achieved by the early work of Froling and Arens. 1) This route was further developed by Corey and Seebach to the generally applicable aldehyde-and ketone-syntheses by using l,+dithisne as a starting substance. 2)
π SIMILAR VOLUMES
MethyZthiomethyZ p-toZyZ sulfone r'l/ can be utizized fofbr synthesizing a-hydroxy ketones as weZZ as a-hydroxy aZdehydes, she hydroxy2 group of which is protected with acetyl, tetrahydropyrany2, or methoxymethy2 group.
An elegant synthesis of cyclic ketones by the reaction of 1,3-dithiane with a,w-dihaloalkanes has been developed by Seebach and Corey.
Contains A Database Of Approximately 70,000 Reactions And 4000 Of The Most Frequently Consulted Reagents. Fully Searchable By Structure And Sub-structure, Reagent, Reaction Type, Experimental Conditions, And Keyword. Also Includes A Searchable Interface: Acronym Finder (an Interface For Scientific A