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A Versatile Enantioselective Strategy Toward l - C -Nucleosides: A Total Synthesis of l -Showdomycin

โœ Scribed by Trost, Barry M.; Kallander, Lara S.


Book ID
121371400
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
254 KB
Volume
64
Category
Article
ISSN
0022-3263

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C-nucleosides and related compounds X sy
โœ George Just; Sunggak Kim ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 156 KB

Pyrazofurin A (VIII) and showdomycin (IV) are nucleosides havin? marked antiviral, antibacterial and antitumor activity2, and their syntheses have been re-ported3r4. We should like to describe the synthesis of their carbocyclic analogues IX and V. The readily available olefin ester I 5 was ozonoly