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A versatile approach to the synthesis of highly functionalised carbocycles

✍ Scribed by Huib Ovaa; Jeroen D.C. Codée; Bas Lastdrager; Herman S. Overkleeft; Gijs A. van der Marel; Jacques H. van Boom


Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
220 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis


A synthetic route towards conduramine and carbasugar derivatives based on the transformation (i.e. two-carbon Wittig olefination and ester reduction) of the Vesella rearrangement product derived from D-galacto6e followed by either a [3,3] Overman or a [2,3]-Wittig-Still sigmatropic rearrangement, and subsequent ring-closing metathesis, is presented.


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