A Vector Model of Adiabatic Decoupling
β Scribed by Thomas E Skinner; M.Robin Bendall
- Book ID
- 102596535
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 298 KB
- Volume
- 134
- Category
- Article
- ISSN
- 1090-7807
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β¦ Synopsis
A vector model of adiabatic decoupling is enunciated for an IS-coupled system of two spin-1 2 heteronuclei in the high-power limit of ideal adiabatic pulses. The observed S-spin magnetization evolves according to a time-dependent coupling that scales as the z component of an I-spin vector which evolves due to the applied decoupling irradiation. Simple analytical expressions are derived both on and off resonance for the reduced coupling during an ideal sech/tanh inversion pulse and for the resulting signal when either in-phase or antiphase magnetization is present at the start of decoupling. The resulting model allows one to readily envision decoupling experiments, make accurate estimates of sideband intensity, and assess the relative performance of different decoupling schemes. The utility of the model is further demonstrated by applying it to several recently proposed methods for reducing sidebands. In the limit of ideal adiabatic pulses, the predictions of the vector model are almost identical to those of quantum mechanics. At the lower RF power levels used in practical adiabatic decoupling applications, where the pulses are no longer perfectly adiabatic, phase cycles are employed to achieve performance that approximates the ideal limits derived here, so the vector model is more generally applicable, as well. These limits establish standards for future determination of the most efficient parameters for practical applications of broadband adiabatic decoupling in a single transient.
π SIMILAR VOLUMES
Adiabatic decoupling is as dependent on well-designed inversion pulse can be a sizable fraction of 1/J. However, phase cycles for performance as any broadband method. pulse length and RF field strength can be varied indepen-For example, the dramatic performance gains of STUD (1) dently in adiabatic
The appearance of sidebands in adiabatic decoupling can be where J max and J min are the maximum and minimum cousubstantially reduced simply by matching the sweep rate and diplings to be decoupled. ## rection of adiabatic pulses with the evolution of different J cou- The subharmonic sidebands whi