Multiple-quantum EPR coherence phenomena in a photo-induced spin-correlated radical pair system are examined. Because of the special singlet-triplet mixing mechanism, we have proposed a phase-cycled two-pulse sequence to excite and detect the single-quantum as well as the normally forbidden zero-and
โฆ LIBER โฆ
A vector description of multiple-quantum coherence in AXn spin systems
โ Scribed by R.M Lynden-Bell; J.M Bulsing; D.M Doddrell
- Publisher
- Elsevier Science
- Year
- 1983
- Weight
- 960 KB
- Volume
- 55
- Category
- Article
- ISSN
- 0022-2364
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Intermolecular zero-quantum coherences (iZQC) induced by the dipolar demagnetizing field can give both P-and N-type cross peaks. This paper shows that the relative intensities of the two types of iZQC peaks follow a simple relation, tan 2 (/2), from both the quantum (spin density matrix) and classic