✦ LIBER ✦

A variable energy valence level photoelectron study of Os(CO)4PMe3: the Os 5d assignment using np → nd resonances

✍ Scribed by Harry B. Davis; Roland K. Pomeroy; Yong-Feng Hu; G.Michael Bancroft; Kim H. Tan

Publisher: Elsevier Science
Year: 1996
Tongue: English
Weight: 356 KB
Volume: 252
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(96)00113-3

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✦ Synopsis

The high resolution valence level photoelectron spectra of Os(CO)4PMe 3 using He I and He I1 laboratory Sources and synchrotron radiation, are reported. The binding energies of the osmium 5p core orbitals have also been determined. The metal 5p ~ 5d resonances were observed using variable energy synchrotron radiation, and have been successfully used to assign the osmium 5d valence orbitals.