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A unique stereospecific [.pi.2s + .sigma.2a] cycloaddition of tetracyanoethylene to substituted cyclopropanone acetals

โœ Scribed by Wiering, Petrus G.; Verhoeven, Jan W.; Steinberg, Herbert


Book ID
126081761
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
270 KB
Volume
103
Category
Article
ISSN
0002-7863

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Triazolines. XXXIII. Nonregiospecific 1,
โœ Zhaiwei Lin; Pankaja K. Kadaba ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Journal of Heterocyclic Chemistry ๐ŸŒ English โš– 530 KB

The 1,3-cycloaddition of aryl azides to the olefinic bonds of 4- and 2-vinylpyridines has been found to yield pyridyl substituted aziridines as the main reaction products with only smaller amounts of the normally expected 1-aryl-5-pyridyl-1,2,3-triazolines. Theoretical and experimental evidence are