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A Unique Binaphthyl Strapped Iron–Porphyrin Catalyst for the Enantioselective Epoxidation of Terminal Olefins

✍ Scribed by Eric Rose; Qi-Zhi Ren; Bruno Andrioletti


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
201 KB
Volume
10
Category
Article
ISSN
0947-6539

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✍ M. Bonnet; L. Schmid; A. Baiker; F. Diederich 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 212 KB 👁 2 views

A new hybrid organic±inorganic material has been obtained by the incorporation of a manganese(III) porphyrin into a mesoporous aerogel matrix. The new heterogeneous catalyst was active in the epoxidation of a variety of olefins and polycyclic aromatic hydrocarbons, using iodosylbenzene as oxidizing