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A unique 1D ribbon coordination polymer containing 2+1 trimeric copper(II) linked by in situ generated polynitrogen heterocyclic ligand as bridges: Synthesis, crystal structure and magnetism

✍ Scribed by Sun, Feng; Yin, Zheng; Zeng, Ming-Hua


Book ID
122386796
Publisher
Elsevier Science
Year
2014
Tongue
English
Weight
237 KB
Volume
46
Category
Article
ISSN
1387-7003

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Two new polynuclear complexes of Cu II , [Cu 2 (fum)(µ-OH)(bpy) 2 (H 2 O)](NO 3 )•2H 2 O (1) (fum = fumarate dianion, bpy = 2,2Ј-bipyridine) and [Cu(fum)(tmen)]•2H 2 O (2) (tmen = N,N,NЈ,NЈ-tetramethylethane-1,2-diamine), have been synthesized and structurally characterized by X-ray crystallography.