A unifying scheme for the electrochemical oxidation of carbonaceous fuels on platinum in sulphuric acid
β Scribed by J.A. Shropshire
- Publisher
- Elsevier Science
- Year
- 1967
- Tongue
- English
- Weight
- 320 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0013-4686
No coin nor oath required. For personal study only.
β¦ Synopsis
Abstraet--A generalized scheme for the electrochemical oxidation of carbonaceous fuels on platinum in sulphurie acid is proposed. Characteristics of the electrochemical oxidation of low molecular weight oxygenated fuels, paratfms and olefins are considered in light of a "two-site" surface. The nature of oscillatory phenomena in these systems is discussed.
R6mma6---Proposition d'un sch6ma g6n~ralis6 de l'oxydation 61ectrochimique de combustibles charhonneux, sur platine darts l'aeide sulfurique. Les caract6dstiques de l'oxydation 61ectrochimique des. combustibles oxyg6n6s de faible poids mol6culaire, des parafines et des ol6fines, sont consid6r6es selon le module d'une surface "~t deux sites". Discussion de la nature du ph6nom~ne oscillant darts ces syst~mes. Zusammeafsslnmg--Man schl~igt ein verallgemeinertes Reaktionsschema ftir die elektrochemische Oxydation yon organischen Brennstoffen an Platin in schwefelsaurer LSsung vor. Die charakteristischen Gesichtspunkte der elektrochemischen Oxydation von niedermolekularen, sauerstoffhaltigen Brennstoffen, von Paraffmen und Olefinen werden mit Hinblick auf eine 2 Arten von aktiven Stellen aufweisende Elektrodenoberfl~iche diskutiert. Man bespricht die
π SIMILAR VOLUMES
The adsorptlon and oxldatlon of acetaldehyde at polycrystalhne platmum In perchlonc acid solution was studled by IFI SI~U SNIFTIR-spectroscopy Carbon dloxlde and acetlc acid were ldentdied m the thm layer as soluble oxidation products m concentrated acetaldehyde solutions At low acetaldehyde concent