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A Uniform Bimetallic Rhodium/Iron Nanoparticle Catalyst for the Hydrogenation of Olefins and Nitroarenes

✍ Scribed by Ikuse Nakamula; Dr. Yoshinori Yamanoi; Dr. Takane Imaoka; Prof. Kimihisa Yamamoto; Prof. Hiroshi Nishihara


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
779 KB
Volume
123
Category
Article
ISSN
0044-8249

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A highly enantioselective rhodium cataly
✍ Dr. Felix Spindler; Ulrich Pittelkow; Hans-Ulrich Blaser πŸ“‚ Article πŸ“… 1991 πŸ› John Wiley and Sons 🌐 English βš– 529 KB

The enantioselective hydrogenation of several a-keto acid derivatives with rhodium diphosphine catalysts has been investigated using a random screening approach. The neutral rhodium catalyst prepared in situ from bis(2,5norbornadiene rhodium chloride) and NORPHOS has been found to be an excellent ca