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A Unified Synthetic Strategy for the Indolopyridine Alkaloid Group

✍ Scribed by Rodolfo Lavilla; Francisco Gullón; Joan Bosch

Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
164 KB
Volume
1999
Category
Article
ISSN
1434-193X

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✦ Synopsis

Thermal or acetyl chloride induced cyclization of bromo-intermediate, palladium-catalyzed reactions allow the total synthesis of indolopyridine alkaloids 1-6. enamide 10 affords the pentacyclic derivative 12 with high yield and regioselectivity. From this common synthetic Extensive studies on the total synthesis of these alkaloids [a] Laboratory of Organic Chemistry, Faculty of Pharmacy, University of Barcelona,

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