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A unified mathematical treatment of diffusion-controlled voltammetric processes

✍ Scribed by I. Fried; E. Shamir

Publisher
Elsevier Science
Year
1969
Tongue
English
Weight
434 KB
Volume
14
Category
Article
ISSN
0013-4686

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✦ Synopsis

It is shown that concentration/time and current/time curves for stirred solutions approach the corresponding curves for quiet solutions when the time approaches zero, regardless of the nature of the electrode reaction and whether the potential of the working electrode is kept constant or not. Moreover, the critical time where the difference between the two current/time curves just exceeds experimental error is computed and compared to the experimental data.

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