✦ LIBER ✦
A two steps ligand exchange reaction of ε-caprolactam stannic chloride complex with cyclohexanone oxime mediated by ammonium chloride
✍ Scribed by M. Masaki; I. Uchida; H. Yasuno; N. Morimoto
- Book ID
- 104234501
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- French
- Weight
- 160 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Although much interest in coordination complexes of amides with stannic chloride has been directed to the structure and the behavior in solution, 1)
reports concerned with the reactivity have scarcely appeared as far as we are aware.
We report here a two steps ligand exchange reaction of &-caprolactam stannic chloride complex (&) with cyclohexanone oxime (L), in which ammonium chloride was used as a medium carrying stannic chloride. An overall representation of the reaction, which is available for an e-caprolactam synthesis, is illustrated in Scheme I.
Scheme I.