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A Two-Dimensional Polyrotaxane with Large Cavities and Channels: A Novel Approach to Metal–Organic Open-Frameworks by Using Supramolecular Building Blocks

✍ Scribed by Eunsung Lee; Jaheon Kim; Jungseok Heo; Dongmok Whang; Kimoon Kim

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
212 KB
Volume
113
Category
Article
ISSN
0044-8249

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A Two-Dimensional Polyrotaxane with Larg
A Two-Dimensional Polyrotaxane with Large Cavities and Channels: A Novel Approach to Metal–Organic Open-Frameworks by Using Supramolecular Building Blocks
✍ Eunsung Lee; Jaheon Kim; Jungseok Heo; Dongmok Whang; Kimoon Kim 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 212 KB 👁 1 views

A seven-membered molecular necklace composed of six copper ions and six pseudorotaxane units behaves as a secondary building block in the formation of a two-dimensional polyrotaxane network with large voids. This novel metal-organic framework allows size-selective anion exchange as well as the excha