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A tunneling spectroscopy study of the adsorption of ferrocyanide from water solution by Al2O3

✍ Scribed by K.W. Hipps; Ursula Mazur; M.S. Pearce


Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
419 KB
Volume
68
Category
Article
ISSN
0009-2614

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✦ Synopsis


limnelin~ spectra of Fe("'C'%)~-and Fe(e("C'4N)~w~dsorbed on A1103 from dilute II+ *60 and 50% H?_"O solutions are compared to infrared and Raman spectra of the K4Fe(CN)6 salt_ C-N stretching frequencies and isotopic shifts indicate that the iron remains in the dixdent state after r?dsorption. IETS provides more information than IR. and sometrhst different information than Rzunan spectroscopy.


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Mechanistic information regarding \(\mathrm{Cr}\) (III) adsorption onto \(\gamma-\mathrm{Al}_{2} \mathrm{O}_{3}\) was obtained using the triple layer model (TLM) in conjunction with experimental data gathered using the pressurejump technique. Adsorption data and TLM simulation results suggest the fo