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A trinuclear copper complex, [Cu3L2](ClO4)2, where H2L is 1,3-bis(2-hydroxy­benzoyl­imino)­propane

✍ Scribed by Yang, Shi-Ping ;Hong, Yang ;Chen, Hong-Mei ;Zhang, Fan ;Chen, Qiong-Qiong ;Yu, Xi-Bin


Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
193 KB
Volume
60
Category
Article
ISSN
1600-5368

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Treatment of 1,3-bis(4-pyridyl)propane with Co(II)(ClO 4 ) 2 or Ni(II)(ClO 4 ) 2 gives isostructural one-dimensional coordination polymers. The metal ions have an octahedral geometry and are bridged by two crystallographically independent ligands along each chain. Alongside each coordination chain a