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A triclinic polymorph of bis(μ 2 -ethanethiolato)-1:2κ 2S : S ;3:4κ 2S : S -(μ 4 -disulfido-1:2:3:4κ 4S : S : S ′: S ′)tetrakis[tricarbonyliron(II)](2 Fe — Fe )

✍ Scribed by Si, Youtao; Chen, Hui; Chen, Chang Neng


Book ID
121738862
Publisher
International Union of Crystallography
Year
2011
Tongue
English
Weight
756 KB
Volume
67
Category
Article
ISSN
1600-5368

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✍ Varga, Richard A. ;Silvestru, Cristian 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 784 KB

The title compound, [Sn~4~(C~9~H~12~N)~4~S~6~]·CHCl~3~, consists of four [2-(Me~2~NCH~2~)C~6~H~4~]Sn units bridged by six S atoms along with a disordered solvent molecule. The cage-like structure has two four-membered Sn~2~S~2~ rings linked by two S atoms in an Sn~4~S~6~ skeleton. The asymmetry of t