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A Trickle Fixed-Bed Recycle Reactor Model for the Fischer-Tropsch Synthesis

✍ Scribed by Brunner, Kyle M.; Duncan, Joshua C.; Harrison, Luke D.; Pratt, Kyle E.; Peguin, Robson P. S.; Bartholomew, Calvin H.; Hecker, William C.


Book ID
115492353
Publisher
Walter de Gruyter GmbH & Co. KG
Year
2012
Tongue
English
Weight
649 KB
Volume
10
Category
Article
ISSN
2194-5748

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✦ Synopsis


A trickle fixed-bed reactor model for the Fischer-Tropsch synthesis applicable to both cobalt and iron catalysts which accounts for gas and liquid recycle is described. A selection of kinetic models for both iron and cobalt catalysts (4 each) is included in the reactor model and their effect on model predictions is compared. While the model is 1-D and reaction rates are determined for quasi-average radial bed temperatures, a correlation is used to account for radial thermal conductivity and radial convective heat transfer. Traditional pressure drop calculations for a packed column were modified with a correlation to account for trickle-flow conditions. In addition to describing the model in detail and showing validation results, this paper presents results of varying fundamental, theoretically-based parameters (i.e. effective diffusivity, Prandtl number, friction factor, etc.). For example, the model predicts that decreasing effective diffusivity from 7.1E-09 to 2.8E-09 m 2 /s results in a lower maximum temperature (518 K vs. 523 K) and a longer required bed length to achieve 60% conversion of CO (8.5 m vs. 5.7 m). Using molar averages of properties to calculate the Prandtl number for the gas phase (recommended by the authors) results in average bed temperatures up to 10 K higher and reactor lengths 17-45% shorter than assuming a Prandtl number of 0.7. Using the Tallmadge equation to estimate friction losses, as recommended by the authors, results in a pressure drop 40% smaller than using the Ergun equation. Validation of the model was accomplished by matching published full-scale plant data from the SASOL Arge reactors.


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