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A tribenzo modified 1,3-calix[4]-bis-crown-6: A highly selective receptor for cesium

✍ Scribed by Zouhair Asfari; Véronique Lamare; Jean-François Dozol; Jacques Vicens

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
189 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis

It is reported the synthesis of calix[4]-bis-(tribenzo)crown-6 I consisting of a calix[4]arene fixed in the 1,3-alternate conformation by the 1,3-and 2,4-bridges made of two modified polyether chains in which the three central ethylene links have been replaced by three 1,2-phenylenes. Ligand 1 complex cesium cation and not sodium one.

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