## Abstract The synthesis and X‐ray structure (as the tetrahydrate) of the platinum(IV) complex __trans,trans,trans__‐[Pt(N~3~)~2~(OH)~2~(NH~3~)~2~] 3 are described and its photochemistry and photobiology are compared with those of the __cis__ isomer __cis__,__trans,cis__‐[Pt(N~3~)~2~(OH)~2~(NH~3~)
A trans-Platinum(II) Complex as a Single-Molecule Insulator
✍ Scribed by Marcel Mayor; Carsten von Hänisch; Heiko B. Weber; Joachim Reichert; Detlef Beckmann
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 136 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0044-8249
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CICYT (Grants SAF00-0029 and SAF 03-01700) and Wellcome Trust (Edinburgh Protein Interaction Centre) for support, Dr. John Parkinson, Dr. Claudia Blindauer and Dr. Juraj Bella for their help and advice with NMR experiments, and colleagues in the EC COST D20 for support and stimulating discussions.
## Abstract The mechanism of substitution water exchange reactions in square planar trans‐Pt[(NH~3~)~2~T(H~2~O)]^n+^ complexes is studied (TH~2~O, NH~3~, OH^−^, F^−^, Cl^−^, Br^−^, H~2~S, CH~3~S^−^, SCN^−^, CN^−^, PH~3~, CO, CH~3~^−^, H^−^, C~2~H~4~). The trans effect is explained in terms of σ‐do