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A tracer study of the persulfate–bisulfite-catalyzed polymerization of acrylonitrile

✍ Scribed by Y. Tsuda


Publisher
John Wiley and Sons
Year
1961
Tongue
English
Weight
337 KB
Volume
5
Category
Article
ISSN
0021-8995

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The molecular weight distribution has been derived for a homopolymer polymerized in a continuous-feed reactor under homogeneous conditions. The derived equations are then compared with data obtained on polymers of acrylonitrileco(viny1 acetate) prepared under heterogeneous conditions with the potass

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## Abstract The polymerization kinetics of acrylonitrile (AN) with the potassium persulfate (K~2~S~2~O~8~)/thiourea redox system has been investigated volumetrically in an aqueous medium in the temperature range of 40–80°C. The rate of polymerization (__R__~__p__~) and rate of K~2~S~2~O~8~ disappea