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A toughened epoxy resin by silica nanoparticle reinforcement

✍ Scribed by P. Rosso; L. Ye; K. Friedrich; S. Sprenger


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
423 KB
Volume
100
Category
Article
ISSN
0021-8995

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✦ Synopsis


Abstract

Within this study the influence of adding 5 vol % of silica nanoparticles, obtained via a sol–gel process, on an Araldite‐F epoxy was investigated. To characterize toughening effects, compact tension specimens were used to obtain K~IC~ and G~IC~. Additionally, tensile strength and E‐Modulus were measured as well as differential scanning calorimetry and dynamic mechanical thermal analysis were carried out to evaluate the influence on the thermal properties of the epoxy because of addition of the particles. Electronic microscopy was used to check dispersion quality and fracture surfaces, in transmission mode and scanning mode, respectively. The addition of 5 vol %. silica‐nanoparticles could improve the stiffness and the toughness of an epoxy resin at the same time. Β© 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 1849–1855, 2006


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Poly(propylene carbonate) (PPC) was used as a toughening agent for improving the brittleness of cured epoxy resins (EP). Methyl tetrahydrophthatic anhydride (MTHPA) was used as a curing agent. The activation energies for the reactions of PPC/MTHPA and EP/MTHPA measured by FTIR were 115.8 and 66.5 kJ