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A Total Synthesis of Verbenachalcone, a Bioactive Diaryl Ether from Verbena littoralis.

✍ Scribed by Takamasa Tanabe; Fuminao Doi; Takahisa Ogamino; Shigeru Nishiyama

Book ID
101965358
Publisher
John Wiley and Sons
Year
2004
Weight
58 KB
Volume
35
Category
Article
ISSN
0931-7597

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## Abstract The first total synthesis of prionoid E (**1**), a rearranged secoabietane diterpene quinone isolated from __Salvia prionitis__, was achieved efficiently by means of __Wacker__ oxidation (__Schemeβ€…5__) and aldol condensation (__Schemeβ€…7__) as the key steps in the synthetic sequence. Thu