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A total synthesis of (±)-frondosins A and B

✍ Scribed by Goverdhan Mehta; Nachiket S. Likhite

Book ID: 104095891
Publisher: Elsevier Science
Year: 2008
Tongue: French
Weight: 224 KB
Volume: 49
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2008.09.163

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✦ Synopsis

A total synthesis of the bioactive meroterpenoid natural products frondosin B and frondosin A (formal) from readily available cyclohexanone and gentisic aldehyde dimethyl ether, involving RCM as the key step to generate the bicyclic 6,7-fused core structure, is outlined.

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