𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A time-resolved technique for measuring rates of alkyl radical-atom reactions: The pressure dependence of the CH3 + H reaction at 504 K

✍ Scribed by Mark Brouaŕd; Martyn T. Macpherson; Michael J. Pilling; James M. Tulloch; Andrew P. Williamson

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
456 KB
Volume
113
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Rate constants for the gas-phase reactio
Rate constants for the gas-phase reactions of OH radicals and Cl atoms with n-alkyl nitrites at atmospheric pressure and 298 K
✍ Ole J. Nielsen; Howard W. Sidebottom; Michael Donlon; Jack Treacy 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 823 KB

## Abstract Rate constants for the reactions of OH radicals and Cl atoms with CH~3~ONO, C~2~H~5~ONO, __n__‐C~3~H~7~ONO, __n__‐C~4~H~9~ONO, and __n__‐C~5~H~11~ONO have been determined at 298 ± 2 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rat

Rate constants at 295 K for the reaction
Rate constants at 295 K for the reactions of atomic chlorine with H2O2, HO2, O3, CH4 and HNO3
✍ Ming-Taun Leu; W.B. Demore 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 516 KB

Constants of the rawions of Cl with HIOz. IX&, 03, CH4, and HNC)J wertt mezxured at 295 K using a flaw discharge-mass spectrometric method. The rate consmts are, WpectiveIy, (6.2 ?c I.51 X 10qzS, (32&) x 10"tl, (1.3 -+. 0.3) X lo-'t, (1.2 ?t 0.3) X 10-13, and (6.8 t 3.4) X lO-is cm3/s.

Measurement of absolute rate data for th
Measurement of absolute rate data for the reaction of atomic potassium, K(42S½), with CH3F, C2H5F, C6H5F, CH3Br, C2H5Br, HCl and HBr by time-resolved atomic resonance absorption spectroscopy at λ = 404 nm (K(52PJ) ← K(42S½))
✍ D. Husain; Y. H. Lee 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 English ⚖ 846 KB

We present a kinetic study of atomic potassium in its electronic ground state, K(4'SI 21, generated in the "single-shot mode" by pulsed irradiation at elevated temperatures and monitored by time-resolved atomic resonance absorption spectroscopy using the Rydberg doublet at A = 404 nm (K[5'PJ] +K[42S

Determination of absolute rate data for
Determination of absolute rate data for the reactions of atomic sodium, Na(32S1/2), with CH3F, CH3Cl, CH3Br, HCl, and HBr as a function of temperature by time-resolved atomic resonance spectroscopy
✍ David Husain; Paul Marshall 📂 Article 📅 1986 🏛 John Wiley and Sons 🌐 English ⚖ 770 KB

We present a kinetic study of the reactions of ground-state sodium atoms with the molecules CH3F, CH3Cl, CH3Br, HC1, and HBr a t elevated temperatures (537-966 K). Na(32S,,2) was generated by the pulsed irradiation of various sodium halide vapors and monitored by time-resolved atomic resonance absor

Temperature dependence of the reaction r
Temperature dependence of the reaction rate constants for O(3P) atoms with C2H4, C3H6 and NO(M = N2O), determined by a modulation technique
✍ R. Atkinson; J.N. Pitts Jr. 📂 Article 📅 1974 🏛 Elsevier Science 🌐 English ⚖ 330 KB

Ra?e constants for the reaction of 0(3P) atoms with CaH4, CaHB and NO(M = NpO) have been measured over the temperature range 300-392°K using a modulation-phase shifi technique. The Arrhenius expressions obtained are: C2H4, k2 = 3.37 X 10' exp[-(1270 -f 200)/RT] liter mole-' see-', CJH~, kz = 2.08 x