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A time-resolved EPR study of the magnetic and decay properties of short-lived non-phosphorescent 3nπ* pyridazine

✍ Scribed by Masahide Terazima; Seigo Yamauchi; Noboru Hirota


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
377 KB
Volume
120
Category
Article
ISSN
0009-2614

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✦ Synopsis


The properries of 'nz* pyridtine u'ere investigawd by time-rcsolvsd EPR. The zfs (X = 0.091 cm-'_ Y = -0.161 cm-'. 2 = 0.071 cm-'), the sublevel decay raw cor~s~~n~s (k. = k-= 2.0~10' 5-l. k,. =1.7x 10' s-') and Ihc relnGvc populaling ra1es (p, : cr : P, = 0.1 : 1 I 0.1) xvere delermined. Th~'lnckbl rn,e CO"SLO"l (k.l= 10h s-1). phosphoracencs is ascribed LO a wry larse radiarionless decay