A Third-Generation Bicyclopropylidene: Straightforward Preparation of 15,15′-Bis(hexaspiro[2.0.2.0.0.0.2.0.2.0.1.0]pentadecylidene) and a C2v-Symmetric Branched [15]Triangulane
✍ Scribed by Malte von Seebach; Sergei I. Kozhushkov; Roland Boese; Jordi Benet-Buchholz; Dmitrii S. Yufit; Judith A. K. Howard; Armin de Meijere
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 181 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0044-8249
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By means of alternating current electrochemical synthesis crystals of [C 13 H 15 N 2 ] + 2 [CuCl 2.58 Br 1.42 ] ± (I) and [C 13 H 15 N 2 ] + [Cu 2 Cl 0.67 Br 2.33 ] ± (II) have been obtained and structurally characterized. Compound I crystallizes in the orthorhombic system, space group Fddd, a = 7.8
The blue mixed-crystal title compound Na 15 [Mo VI 126 Mo V 28 O 462 H 14 (H 2 O) 70 ] 0.5 [Mo VI 124 Mo V 28 O 457 H 14 (H 2 O) 68 ] 0.5 ´ca. 400 H 2 O º Na 15 [1 a] 0.5 [1 b] 0.5 ´ca. 400 H 2 O 1, which crystallizes in the triclinic space group P 1 (a = 30.785(2), b = 32.958(2), c = 47.318(3) A Ê