A thio­phene-based aza­cryptand Mannich base: 18,24-bis­(p-tolyl­sulfonamido)-2,5,8,11,21-penta­oxa-15,27-dithia-18,24-diaza­tricyclo­[24.3.0.0]nona­cosa-1(26),12(16),13,28-tetra­ene

✍ Scribed by Labat, Gaël ;Halfpenny, Joan

• Book ID: 104486985
• Publisher: International Union of Crystallography
• Year: 2006
• Tongue: English
• Weight: 304 KB
• Volume: 62
• Category: Article
• ISSN: 1600-5368
• DOI: 10.1107/s1600536806024317

✦ Synopsis

The title compound, C~34~H~42~N~2~O~9~S~4~, is composed of two thiophene rings bridged by an —O—(CH~2~)~2~—O—(CH~2~)~2~—O— chain and a trisubstitued diamine with pendent tosyl rings. In the crystal structure, the molecules are stabilized by several intra- and intermolecular C—H...O interactions, forming a two-dimensional network arranged in the ac plane.