𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A Thermoresponsive Hydrogel Based on Telechelic PEG End-Capped with Hydrophobic Dipeptides

✍ Scribed by Ian W. Hamley; Ge Cheng; Valeria Castelletto


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
561 KB
Volume
11
Category
Article
ISSN
1616-5187

No coin nor oath required. For personal study only.

✦ Synopsis


Abstract

The self‐assembly in aqueous solution of PEG (1 500 Da) telechelically end‐capped with hydrophobic dipeptides has been investigated using spectroscopic, microscopic, scattering, and rheological methods. A self‐assembled β‐sheet fibril‐based hydrogel has been identified (containing dityrosine end groups), which exhibits a gel–sol transition near body temperature. This thermo‐responsive PEG‐based biofunctional hydrogel is expected to have diverse potential uses in delivery or diagnostics for biomedical applications. magnified image