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A Thermodynamically Based and Definitive Demonstration of the Inadequacy of the ECW Model for Phosphorus(III) Ligands

✍ Scribed by Fernandez, Anthony L.; Lee, Tsung Ying; Reyes, Clementina; Prock, Alfred; Giering, Warren P.

Book ID
125929205
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
118 KB
Volume
17
Category
Article
ISSN
0276-7333

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## Abstract Five DOTA‐like ligands lacking a water molecule in the first coordination sphere of their Gd^III^ complexes, namely the phosphinates H~4~DOTP^H^, H~4~DOTP^hm^ and H~4~DOTP^Et^, and the phosphonate monoesters H~4~DOTP^OEt^ and H~4~DOTP^OBu^, were synthesized with the aim of exploring the