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A Thermodynamic Analysis to Explain the Boiling-Point Isotope Effect for Molecular Hydrogen

✍ Scribed by Baker, D. Blane; Christmas, Byron K.

Book ID
125952812
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
32 KB
Volume
77
Category
Article
ISSN
0021-9584

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πŸ“œ SIMILAR VOLUMES

Secondary hydrogen isotope effect for th
Secondary hydrogen isotope effect for the transition from olefin to free radical
✍ Richard W. Henderson; William A. Pryor πŸ“‚ Article πŸ“… 1972 πŸ› John Wiley and Sons 🌐 English βš– 279 KB

Secondary kinetic isotope effects occur in radical additions to deuterated olefins. Substitution of a deuterium at a carbon undergoing an sp2 to sp3 hybridization-change during reaction, Cg in eq. ( I ) , leads to an The effect at a carbon going from a n olefinic to a radical center, C, in eq. (I),