The slow-motion theory of nuclear spin relaxation in paramagnetic low-symmetry complexes is generalized to comprise arbitrary values of S. We describe the effects of rhombic symmetry in the static zero-field splitting (ZFS) and allow the principal axis system of the static ZFS tensor to deviate from
β¦ LIBER β¦
A theory of the electron spin relaxation from hindered rotations in paramagnetic crystals
β Scribed by Zbigniew Zimpel
- Publisher
- Elsevier Science
- Year
- 1987
- Weight
- 609 KB
- Volume
- 145
- Category
- Article
- ISSN
- 0378-4363
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A direct density matrix treatment of the relaxation processes in dilute paramagnetic solids at high temperature is performed. Using the Βͺdressed stateΒΊ formalism, the theory is developed differently from the one often referred to as the ΒͺRedfield TheoryΒΊ, which uses the concepts of correlation funct