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A theory of the electrical double layer through the Born—Green—Yvon equation

✍ Scribed by Thomas L. Croxton; Donald A. McQuarrie


Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
463 KB
Volume
68
Category
Article
ISSN
0009-2614

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📜 SIMILAR VOLUMES


A simple procedure for deriving an elect
✍ Marcelo C Lozada 📂 Article 📅 1981 🏛 Elsevier Science 🌐 English ⚖ 154 KB

A simple procedure for deriving electrical double layer equations from electrolyte theories is applied to the Born-Green-Yvon equation. It is shown that when the auto-field effects are not considered in the wall-ion potential, the equation obtained with this procedure leads to gross inconsistencies.

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The problem of the statistical distribution of the ions located in the diffuse part of the double layer at the medium/solution interphase is solved for a discrete layer of specitic adsorbed ions is present at this interphase. It is shown that short-range effects between the ions lead to a sharper dr