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A Theoretical−Experimental Approach to the Mechanism of the Photocarbonylation of Chromium(0) (Fischer)−Carbene Complexes and Their Reaction with Imines

✍ Scribed by Arrieta, Ana; Cossío, Fernando P.; Fernández, Israel; Gómez-Gallego, Mar; Lecea, Begoña; Mancheño, Maria J.; Sierra, Miguel A.

Book ID: 126828735
Publisher: American Chemical Society
Year: 2000
Tongue: English
Weight: 93 KB
Volume: 122
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja000706t

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## Abstract The Pd‐ and Rh‐mediated cyclization of group 6 (2‐aminoethenyl)carbene complexes incorporating aryl iodides or boronates in their structures is reported. The process led to the formation of quinoline rings and has been applied to the synthesis of quinoline alkaloids **12** and **13** is