A theoretical study of the structure and reactivity of carbon and graphite layers on nickel surfaces
β Scribed by G.R. Darling; J.B. Pendry; R.W. Joyner
- Publisher
- Elsevier Science
- Year
- 1989
- Weight
- 48 KB
- Volume
- 221
- Category
- Article
- ISSN
- 0167-2584
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Diazomethane has been used to methylate the "active" hydrogen associated with acidic oxides on carbon and graphite surfaces. Analysis of the methoxyl groups so formed showed that the active hydrogen was present as an OH group and that the total active hydrogen content of both carbon and graphite deg
An nb initio LCCO Al0 SCI? olcuhtion with a full geometry srarch is urried out on CC)>. The structure is dctermined to have Czv symmetry with C-O hot??. bngths of 1.265 .A and 1 A73 A and a bond angk of 66.X". The unique oxygen atom is apparently of the cubouyl type and there is a weak bond between