Comprehensive theoretical studies have been made on the effect of initiation and transfer to monomer on the molecular size distribution in living polymers. However, no detailed theoretical investigation involving spontaneous transfer has been reported so far. In the present paper, a study is made of
A theoretical study of the size distribution in reversible anionic polymers
β Scribed by V.S. Nanda; S.C. Jain
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- English
- Weight
- 138 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0014-3057
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## Synopsis A method to produce homopolymers of preestablished molecular weight distribution (MWD), through "living" anionic polymerizations carried out in homogeneous semibatch reactors is proposed and theoretically justified. In the direct form of the technique, very fast reactions are assumed,
Cluster anions of methyl acrylate (MA) and methyl methacrylate (MMA) clusters were produced by electron transfer from high-Rydberg atoms of krypton and the mass spectra of the cluster anions were measured. The intensity of (MA), was particularly enhanced in the size distribution of MA); with an incr