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A theoretical study of the mechanisms of oxidation of ethylene by manganese oxo complexes

✍ Scribed by Aniagyei, Albert; Tia, Richard; Adei, Evans


Book ID
125431438
Publisher
Royal Society of Chemistry
Year
2013
Tongue
English
Weight
645 KB
Volume
42
Category
Article
ISSN
1477-9226

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## Abstract The intrinsic reactivity of a manganese(V)‐oxo porphyrin complex, a typically fleeting intermediate in catalytic oxidation reactions in solution, has been elucidated in a study focused on its gas‐phase ion‐chemistry. The naked high‐valent Mn^V^‐oxo porphyrin intermediate **1** ([(tpfpp)