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A theoretical study of the mechanism of oxidative dihydrogen addition to palladium clusters

✍ Scribed by Victor M. Mamaev; Igor P. Gloriozov; Vahan V. Simonyan; Elena V. Zernova; Andrew V. Prisyajnyuk; Yurii A. Ustynyuk


Book ID
111729995
Publisher
Royal Society of Chemistry
Year
1997
Tongue
English
Weight
159 KB
Volume
7
Category
Article
ISSN
0959-9436

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πŸ“œ SIMILAR VOLUMES


Mechanism of the oxidative addition of a
✍ Jutand, Anny (author);Pytkowicz, Julien (author);Roland, Sylvain (author);Mangen πŸ“‚ Article πŸ“… 2010 πŸ› Walter de Gruyter GmbH 🌐 English βš– 400 KB

Bis-__N__-heterocyclic carbenes Pd^0^ complexes, Pd^0^(NHC)~2~, are efficient catalysts in Heck reactions performed with aryl bromides or chlorides. The Pd^0^(NHC)~2~ that are not stable are generated in situ from Pd^II^ precursors PdY~2~(NHC)~2~ (Y = halides) after a chemical reduction. The latter