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A theoretical study of the insertion of olefins into Timethyl bonds by “Paired Interacting Orbitals”

✍ Scribed by Akinobu Shiga; Hiroshi Kawamura; Takeshi Ebara; Toshio Sasaki; Yasuo Kikuzono


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
667 KB
Volume
366
Category
Article
ISSN
0022-328X

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✍ David A. Horner; Larry A. Curtiss; Dieter M. Gruen 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 392 KB

The insertion of dicarbon (C 2) and vinylidene into methane C-H bonds was studied using ab initio molecular orbital theory. The reactions are simple models for thin film diamond growth in which C 2 is the principal growth species. The results of this study suggest that reaction of C 2 with a diamond