A Theoretical Study of the Inner-Sphere Disproportionation Reaction Mechanism of the Pentavalent Actinyl Ions
โ Scribed by Helen Steele; Robin J. Taylor
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 11 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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โฆ Synopsis
Abstract
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๐ SIMILAR VOLUMES
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In this study, we describe the results of ab initio (HF and MP2) and MNDO-PM3 calculations on the model reactions of unstabilized (Me 3 PโซืกโฌCH-CH 3 ), semistabilized (Me 3 PโซืกโฌCH-CฯตCH), and stabilized (Me 3 PโซืกโฌCH-CฯตN) ylides with acetaldehyde to form their respective Z and E olefins and trimethylph