A Theoretical Study of the Iminoxyl/Oxime Self-Exchange Reaction. A Five-Center, Cyclic Proton-Coupled Electron Transfer

Bis(dithiolene) Molybdenum Complex that

Bis(dithiolene) Molybdenum Complex that Promotes Combined Coupled Electron–Proton Transfer and Oxygen Atom Transfer Reactions: A Water-Active Model of the Arsenite Oxidase Molybdenum Center

✍ Hideki Sugimoto; Makoto Tarumizu; Hiroyuki Miyake; Hiroshi Tsukube 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 116 KB 👁 1 views

## Abstract Combined CEPT (coupled electron–proton transfer)/OAT (oxygen atom transfer) reactions were accomplished in (Bu~4~N)~2~[Mo^IV^O(bdtCl~2~)~2~] (1) and (Bu~4~N)~2~[Mo^VI^O~2~(bdtCl~2~)~2~] (2) complexes in aqueous media. The reaction mechanism of the CEPT reaction was analyzed electrochemi