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A theoretical study of the electronic effect of the ligand bite angle on the hydrosilylation reaction of ketones by Cu(I) diphosphine complexes

✍ Scribed by Thomas Gathy; Olivier Riant; Daniel Peeters; Tom Leyssens


Book ID
116680154
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
507 KB
Volume
696
Category
Article
ISSN
0022-328X

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A CLFSE/MM study on the role of ligand b
✍ Ian W. Davies; Robert J. Deeth; Robert D. Larsen; Paul J. Reider πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 283 KB

A single force-field has been developed for modeling bis(oxazoline) and pyridine-bis(oxazoline) copper(ll)complexes. Using this force field the role of ligand bite-angle on the enantioselectivity of Cu(ll)-catalyzed Diels-Alder was confirmed and for the first time, a direct comparison of the role of