A theoretical study of the catalytic cycle of ethylene hydrogenation by a bipalladium cluster
โ Scribed by Viktor M. Mamaev; Igor P. Gloriozov; Dmitrii A. Lemenovskii; Yurii V. Babin
- Book ID
- 119767808
- Publisher
- Royal Society of Chemistry
- Year
- 2000
- Tongue
- English
- Weight
- 166 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0959-9436
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๐ SIMILAR VOLUMES
The hydration reaction of ethylene, C 2 H 4 + H 2 O โ C 2 H 5 OH, catalyzed by oxoacids (H 3 PO 4 , H 2 SO 4 , and HClO 4 ) and metal cations (B 3+ , Al 3+ , Sc 3+ , Ga 3+ , La 3+ , Be 2+ , Mg 2+ , Ca 2+ , Zn 2+ , and Sr 2+ ) are studied systematically by density functional theory with a BLYP functi
## Abstract The diphosphaneโsubstituted clusters [Ru~3~(CO)~10~(dppe)] and [Ru~3~(CO)~8~(dppe)~2~] [dppe = 1,2โbis(diphenylphosphanyl)ethane] are shown to catalytically hydrogenate diphenylacetylene. This process is highly solventโdependent with fragmentation dominating in lowโpolarity solvents, wh