𝔖 Bobbio Scriptorium
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A theoretical study of the barbier reaction

✍ Scribed by Albert Moyano; Miquel A. Perica´s; Antoni Riera; Jean-Louis Luche

Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
217 KB
Volume
31
Category
Article
ISSN
0040-4039

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✦ Synopsis

Semiempirical MO calculations are shown to provide a more detailed picture of the radical ion mechanism of the Barbier reaction in the general case. Calculated electron affinities give a clue for its extension to other cases. Halides CHs-X nC3H7.X (I!!)CHs-CH=CH-X

📜 SIMILAR VOLUMES

Theoretical study of the O + HSO reactio
Theoretical study of the O + HSO reaction
✍ M. Y. Ballester; A. J. C. Varandas 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 199 KB

## Abstract A quasi‐classical trajectory study of the title reaction is reported using a global, double, many‐body expansion potential energy surface for HSO~2~. Calculations are presented for specific translational energies and rovibrational states of the reactants, showing that formations of H +